Answers to Questions |
1. boric acid = B(OH)3
borax = Na2B4O5(OH)4.8H2O
gypsum = CaSO4.2H2O
alumina = Al2O3
2.
(a) (c)
(d)
(b) because it has 6 valence electrons;
3. borax, Na2B4O5(OH)4.8H2O
= Na2B4O7.10
H2O
kernite, Na2B4O5(OH)4.2H2O
= Na2B4O7.4
H2O
4. bauxite, AlO(OH)
5. The Bayer process:
AlO(OH)(s) + NaOH(aq) + H2O(l)NaAl(OH)4(aq)
SiO2(s) + 2 NaOH(aq)Na2SiO3(aq) + H2O(l)
NaAl(OH)4(aq)Al(OH)3(s) + NaOH(aq)
Al(OH)3(s)Al2O3(s) + H2O
2 AlO(OH)Al2O3 + H2O
2 Al2O34 Al(l) + 3 O2(g)
6. 6 HF + Al(OH)3
+ 3 NaOH Na3AlF6
+ 6 H2O
7. It is the electrochemical process
by which aluminum is obtained from alumina (Al2O3).
The Hall process involves the use of an artificial cryolite ore, Na3AlF6.
which serves to lower the melting point of alimina:
Al2O3/Na3AlF6 + 3 e-Al(l)
8. Boron is the only non-metal
and there are no metalloids; Al, Ga, In, and Tl are all metals.
9. carbon, silicon
10.
11. (a) Td (b) Oh (c) D3h (d) D2h
12. Na = +1; B = +3; O = -2; H = +1
13. ability to conduct electricity, malleability, ductility, luster, etc.
14.
Fe2O3(s)
+ 2 Al(s) 2
Fe(s) + Al2O3
DHf
-822
0
0 -1676
DHrxn = -854 kJ
15.
(a) 2 Ga(s) + 6 HCl(aq)3 H2(g) + 2 GaCl3
(b) 6 H2O + 2 In(s) + 2 OH-(aq)3 H2(g) + 2 [In(OH)4]-
16.
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17. see a periodic table