Step-by-step instructions for generating gases in large plastic syringes. Watch youtube video! Three Easy Gases. CO2, H2 and O2. How to make these gases in syringes, and 20+ chemical experiments and classroom demonstrations with these gases. Seven Laboratory Experiments. High school and university level experiments that explore physical and chemical properties of gases. Link to download these experiments. Mystery gas. Is the gas
H2, O2,
CO2, or
air?
All gases.
Preparation instructions for many interesting gases with
about ten experiments and classroom demonstrations for
each. Gases include NO, NO2,
SO2, C2H2,
O3, NH3,
Cl2, H2S
and ten others.
Percent Composition of CaCO3 in Tums antacid Carbonated Beverages — Priestley’s Soda-water Molar Mass - remarkably accurate results! Limiting Reagent Magnesium + HCl(aq) Barometric Pressure without a barometer Left: Upper syringe had contained colorless NO(g), but as O2(g) is added from the lower syringe, NO2(g) is instantly formed. Right: Underwater fireworks result when Cl2(g) and C2H2(g) are combined in close proximity underwater.
Function
and importance of nanoparticles in catalysis,
This is a 3-part series on Bringing New
Chemistry into
Classroom: Nanoparticles and Catalysis
Series. The first part appeared in Chem13
News, 2017, 435, 12-15.
|
Why Microscale Gas Chemistry?
Our Gas Reaction
Catalyst Tube can be used to demonstrate a variety
of gas phase chemical reactions. The catalyst
contains a layer of disbursed palladium atoms on a
ceramic material and enclosed within a glass housing
as per the figure. Hydrogenation of alkenes occurs
at very temperatures (even < 0 deg C). A
wonderful classroom demonstration shows how a
catalytic converter works by transforming CH4
(or any hydrocarbon) + NO2 (the
reddish mixture in the left syringe below) into N2
+ H2O + CO2 (right
syringe - condensation droplets of water
are often noticed in right syringe).
Gas Bags For classroom use,
gases can be prepared and stored in sealable plastic
food bags equipped with a dispensing tube.
Mini-Ozone Generator Ozone is generated
for in situ use. The Mini-Ozone generator
produces 800 nanomole/minute. Safe and easy to
use. Off the shelf classroom demo that
anyone can build.
Left: Apparatus dispensing O3 to a flask. Right: Close up of the mini-O3 generator showing the pipet bulb reaction chamber in cup of ice. |
Download
content now!
Other links and Downloads History of gas
chemistry
Photographs of Joseph Priestley sites in England along with a chronological summary of his life. Kipp generators Other microscale gas chemistry methods: Link
to download pages for
Gases in your
curriculumThermal methods for making HCl, C2H4, CO, CH4 and N2O Microwave oven method Microscale gas methods by other researchers About us Contact us 18th Century and 21st Century Gas Prep Equipment You are visitor number to this site. Site updated 11 May 2019 Our research group, Spring 2019 |
Build a Gas Reaction Catalyst Tube (Pd
Nanoparticle Catalyst Tube)
Catalyst
tubes such as the one pictured below can be built for
about US$2 each. Details for construction are available that
include chemical tests. Instructions that also
address analysis by MS and NMR are also available.
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On the Hydrogenation
of Alkynes with the
Pd Nanoparticle Catalyst Tube
Alkynes
readily react with H2 or D2 upon passing through the catalyst
tube even at low temperatures. Numerous
experiments support the reaction pathway illustrated
below: Alkyne to alkene via vinyl reversal followed by
alkene to alkane via Horiuti-Polanyi mechanism without
leaving the surface of the palladium catalyst. This
work is currently being performed. |
Incomplete Combustion of H2
Trapping a
Reaction Intermediate. A classroom demonstration or
descriptive chemistry experiment. Journal of Chemical
Education 2007, 84, 1668 - 1670. (Download pdf)
or See
movie of the demo. |
Paramagnetic
Oxygen
"Demonstrating
the Paramagnetism of Liquid Oxygen with a Neodymium
Magnet." A classroom demonstration or descriptive
chemistry experiment. Journal of Chemical Education
2007, 84, 1296 - 1298. Download
pdf. or See
movie
of the demo! |
Propanol to
Propane.
An
advanced laboratory experiment using heterogeneous
catalysts for two successive gas-phase reactions;
appeared in Journal of Chemical Education, March,
2006. Download
as a pdf file. |
H2 and D2 Uptake
on Pd Foil
Hydrogen
and palladium foil. Two classroom
demonstrations. 1. Physical changes that take
place when Pd absorbs H2 and D2.
The kinetics of H2 or D2
uptake. Elsbeth Klotz, E.; and Mattson, B.Journal of
Chemical Education 2009, 86, 465 – 469. (Download
pdf) |
H/D Exchange
in Methane
Using
the Gas Reaction Catalyst Tube and high temperatures,
CH4 exchanges H for D yielding all
combinations CH4, CH3D,
CH2D2, CHD3
and CD4 ultimately in a statistical
distribution. Isotopologues can be identified by
H-NMR and mass spectroscopy. |
Deuteration
of Ethene and 1-butene
Using
the Gas Reaction Catalyst Tube, C2H4
and 1-butene undergo D/H exchange more rapidly than
deuteration, resulting in a complex product
distribution of isotopologues/ isotopomers of ethane-dx
and butane-dx. The reaction follows the
Horiuti-Polanyi mechanism first proposed in
1934. |